| Challenger - Nur-Sultan | 02/23 08:35 | 25 | [194] Alexandre Muller v Brayden Schnur [215] | 6-7,6-3,1-6 | |
| Australian Open | 02/10 01:35 | 24 | [210] Alexandre Muller v Diego Schwartzman [9] | 2-6,0-6,3-6 | |
| Australian Open | 02/08 05:10 | 23 | [209] Alexandre Muller v Juan Ignacio Londero [81] | 4-6,6-3,6-0,6-3 | |
| ATP Murray River Open | 02/02 06:10 | 24 | [209] Alexandre Muller v Nick Kyrgios [47] | 6-3,4-6,6-7 | |
| Australian Open | 01/13 12:10 | 19 | [112] Aslan Karatsev v Alexandre Muller [208] | 6-2,6-1 | |
| Australian Open | 01/12 15:00 | 15 | [217] Peter Polansky v Alexandre Muller [208] | 0-6,1-6 | |
| Australian Open | 01/11 15:05 | 60 | [208] Alexandre Muller v Federico Gaio [136] | 6-1,6-1 | |
| Challenger - Ortisei | 11/21 10:00 | 28 | [214] Alexandre Muller v Antoine Hoang [126] | 6-3,2-6,2-6 | |
| Challenger - Ortisei | 11/20 10:00 | 27 | [214] Alexandre Muller v Illya Marchenko [218] | 6-7,7-6,7-5 | |
| Challenger - Ortisei | 11/18 10:00 | 26 | [214] Alexandre Muller v Jay Clarke [188] | 7-6,6-7,6-3 | |
| Challenger - Ortisei | 11/16 14:20 | 25 | [102] Yasutaka Uchiyama v Alexandre Muller [211] | 3-6,4-6 | |
| Challenger - Parma 2 | 11/03 14:50 | 25 | Kimmer Coppejans v Alexandre Muller | Cancelled |